After spending the summer traveling around Europe with their six children, Brad Pitt and Angelina Jolie enjoyed some adult time together on the red carpet on Friday, and RadarOnline.com has all the photos of their glamorous night out.

The beautiful couple looked a world away from the busy parents we are used to seeing as they were the guests of honor at the premiere of Brad's upcoming move, Moneyball, at the 2011 International Toronto Film Festival.

PHOTOS:  Brad Pitt And Angelina Jolie At Moneyball Premiere In Toronto

Jolie, 36, swapped her casual clothes for a dramatic black satin Vivienne Westwood gown and Stuart Weiztman shoes, but all eyes were on her edgy gold Louis Vuitton clutch, which was attached to her wrist with a studded handcuff!

The fashion statement was a flashback to Angelina's former gothic style before becoming a mother, when she would wear a vial of blood around her neck and flaunt her many tattoos.

PHOTOS: Brad Arrives At Moneyball Press Conference

Hollywood's most famous family has most recently been staying in London as Brad films his upcoming zombie action movie, World War Z. Previous locations for the sure-to-be blockbuster were Glasgow and Malta.

As RadarOnline.com previously reported, 47-year-old Brad looked unusually exhausted on Friday during a press conference for Moneyball after flying from England to Toronto to promote the baseball movie.

PHOTOS: Brad and Angie Take The Kids To See The Smurfs

Moneyball tells the story of the Oakland A's manager Billy Beane who made baseball history when he put a team together on a budget using mathematical analysis and statistics to draft players.

Alongside Pitt, it also stars Jonah Hill, Robin Wright and Philip Seymour Hoffman.

something you’re not telling us Mr. Pitt?!!

RELATED STORIES:

Brad Pitt Is A Real-Life Superhero!

Angelina Is Wasting Away! Jolie Looks Scary Skinny In London

Why Angelina Jolie Had To Be Quarantined From Her Kids

Angelina Jolie: ‘I’m Not Getting Married And I’m Not Pregnant’

The are-they-or-aren't-they dating question has been answered. George Clooney and Stacey Keibler were spotted partying two nights in a row at the Toronto Film Festival.

Clooney was there to premiere his new film, The Ides of March.

PHOTOS: Stacy Keibler Takes On George Clooney’s Gorgeous Exes In Bikini Wars

George and the Dancing with the Stars alum didn't walk the red carpet together but were very much a couple at the after-party at Deq in the Ritz-Carlton, where they were also spotted together the night before, reports People.

They were equally the "life of the party," a source said, adding that the pair left hand-in-hand.

PHOTOS: Elisabetta Canalis In A Bikini

Ironically, Clooney's most recent honey, Elisabetta Canalis is competing on the new season of DWTS, premiering September 19.

PHOTOS:  Dancing With The Stars Season 13 -- All The Sexy Cast Portraits

RELATED STORIES:

DWTS: Elisabetta Canalis Is Smoking Hot -- Chaz Bono & Lacey Schwimmer Head To Rehearsals

Ricki Lake Becomes First Casualty Of The New DWTS Season

George Clooney And Stacy Keibler - Can Their Long Distance Romance Survive?

George Clooney's Ex Elisabetta Canalis 'Down In The Dumps' Following Split, Says Mother

Considering Brad Pitt has a seemingly perfect life, with a red hot career, beautiful children, millions in the bank and a gorgeous life partner in Angelina Jolie , you would think he would be all smiles.

But the 47-year-old father of six was looking somewhat exasperated Friday as he sat through a press conference for his new movie Moneyball at the 36th Toronto Film Festival in Canada.

PHOTOS: Brad Arrives At Moneyball Press Conference