Angelina Jolie was drop dead gorgeous on the red carpet in her tight leather pencil skirt and RadarOnline.com has the photos of her super sexy ensemble.

With Brad Pitt on her arm, Angelina’s naughty school teacher look sizzled on the red carpet when she stepped out in a Salvatore Ferragamo black leather skirt and low cut blouse that showed off her stunning figure.

The Hollywood power couple held hands as they attended the 77th Annual New York Film Critics Circle Awards Gala in NYC Monday night, and Brad was honored with a best actor award for his roles in Moneyball and Tree of Life.

Doesn’t she get tired of reigning red carpets? Just when we thought it couldn’t get any hotter than the vision of Angelina Jolie at the Moscow premiere of Salt in her red Atelier Versace dress, the brunette bombshell hit the Tokyo premiere in another masterpiece a la mode.

PHOTOS: Angelina Takes Tokyo By Storm

This time the spygirl style siren opted for a vintage Versace gown, which flawlessly draped across her body in the best way possible. The dramatically slit, turtleneck gown, featured a cutout back, which exposed her intricately inked tattoos.

PHOTOS: Angelina’s Spygirl Style Spree

With her hair pulled into a neat updo, the actress rocked stunning emerald earrings in her lobes and a naturally made up face.

PHOTOS: Angelina’s Sexy Star Style Evolution

What other one of Angie’s fave designers did she rock to the Tokyo photocall for Salt? Check out the gallery in Style and find out.