Angelina Jolie shows what happens when two worlds collide as she talks about poverty stricken Cambodia, while posing for a multimillion dollar ad campaign for Louis Vuitton and RadarOnline.com has the video.

While there is no doubt, the charitable star is selflessly dedicated to her work as a Goodwill Ambassador for the United Nations, her latest Core Values ad for the luxury luggage company certainly has a whiff of irony about it.

PHOTOS: Angelina & The Kids In Hollywood

Oscar winner, humanitarian, United Nations Goodwill Ambassador, mother of six - now Angelina Jolie can add Louis Vuitton model to her illustrious resume as she graces the luxury designer's new fashion campaign, and RadarOnline.com has the first photo from the glamorous shoot.

True to her charitable roots, instead of dripping with jewels in Paris or being romanced in Rome, fresh-faced Jolie posed for the company's Core Values campaign floating wistfully on a wooden boat on an idyllic lakeside in Cambodia's Sieme Reap province.

PHOTOS: Angelina Jolie Over The Years

Wearing no shoes or make-up, the ethereal star was captured by famed photographer Annie Leibowitz while she stared peacefully into the distance alongside her own well-used monogrammed Alto Vuitton bag.